Structural Development and Rubber Elasticity of Segmented Polyurethanes.
نویسندگان
چکیده
منابع مشابه
Synthesis and surface properties of environmentally responsive segmented polyurethanes.
Polyurethanes, containing well-defined assemblies of perfluoro-polyether (PFPE or hexafluoropropene oxide oligomer), polydimethylsiloxane (PDMS), and polyethylene glycol (PEG) segments, exhibit oleophobic, hydrophobic, and hydrophilic properties in response to the polarity of the contacting medium. These polymers were prepared by reacting hydroxy(polyethyleneoxy)-propylether-terminated PDMS blo...
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The effects of thermal elastic fluctuations in rubbery materials are examined. It is shown that, due to their interplay with the incompressibility constraint, these fluctuations qualitatively modify the large-deformation stress-strain relation, compared to that of classical rubber elasticity. To leading order, this mechanism provides a simple and generic explanation for the peak structure of Mo...
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Controlling the non-specific adsorption of proteins, cells and bacteria onto biomaterial surfaces is of crucial importance for the development of medical devices with specific levels of performance. Among the strategies pursued to control the interactions between material surfaces and biological tissues, the immobilization of non-fouling polymers on biomaterial surfaces as well as the synthesis...
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1. Abstract Phase separation in segmented polyurethanes is an important phenomenon, which affects on characteristic properties of polyurethanes. Morphology, formation and distribution of micro-domains (hard segments and soft segments) are effective parameters on interfacial interaction and adhesion of polyurethane system. In this work segmented polyurethanes based on 4,4 -diphenylmethane diisoc...
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The single most important property of elastomers—that from which their name derives—is their ability to undergo large elastic deformations, that is, to stretch and return to their original shape in a reversible way. Theories to account for this characteristic high elasticity have passed through three distinct phases: the early development of a molecular model relating experimental observations ...
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ژورنال
عنوان ژورنال: Kobunshi
سال: 1992
ISSN: 0454-1138,2185-9825
DOI: 10.1295/kobunshi.41.204